Publications

(57) “A Unified Explanation for Chemoselecivity and Stereospecificity of Ni-Catalyzed Kumada and Cross-Electrophile Coupling Reactions of Benzylic Ethers: A Combined Computational and Experimental Study”
Chen, P.; Lucas, E.; Greene, M. A.;  Zhang, S.; Tollefson, E.J.; Erickson, L.; Taylor, B.L.;  Jarvo, E.R.; Hong, X. J. Am. Chem. Soc. 2019141, 5835–5855.
DOI: 10.1021/jacs.9b00097

(56) “Outer-Sphere Control for Divergent Multicatalysis with Common Catalytic Moieties” Shugrue, C. R.; Sculimbrene, B. R.; Jarvo, E. R.; Mercado, B. Q.; Miller, S. J.* J. Org. Chem. 2019, Just accepted.  DOI: 10.1021/acs.joc.8b03068

(55) “Nickel-Catalyzed Directed Hydroarylation of Alkynes with Boronic Acids” Hanna, L. E.; Konev, M.; Jarvo, E. R. Eur J. Org. Chem. 2019, 184-187.  DOI: 10.1002/ejoc.201801494

(54) “Keeping Track of Electrons” Lucas, E.L.; Jarvo, E.R. Acc. Chem. Res. 2018, 51, 567-572. DOI: 10.1021/acs.accounts.7b00432(53) “Nickel-Catalyzed Hydrogenolysis and Conjugate Addition of 2-(Hydroxymethyl)pyridines via Organozinc Intermediates” Hanna, L. E.; Harris, M. R.; Domon, K.; Jarvo, E. R. Org. Lett. 201719, 6304-6307.
DOI: 10.1021/acs.orglett.7b03049

(52) “Mechanism and Origins of Ligand-Controlled Stereoselectivity of Ni-Catalyzed Suzuki–Miyaura Coupling with Benzylic Esters: A Computational Study.” Zhang, S.; Taylor, B. L. H.; Ji, C.; Gao, Y.; Harris, M. R.; Hanna, L. E.; Jarvo, E. R.; Houk, K. N.; Hong, X. J. Am. Chem. Soc. 2017139, 12994–13005.
DOI: 10.1021/jacs.7b04973

(51) “Stereospecific and stereoconvergent cross-couplings between alkyl electrophiles.” Lucas, E. L.; Jarvo, E. R. Nat. Rev. Chem. 20171, 0065.
DOI: 10.1038/s41570-017-0065

(50) “Nitroxyl Surprise: A Simple Amine Additive Revealed as Copper’s Co-Catalyst in the Aerobic Oxidation of Alcohols” Konev, M. O.; Jarvo, E. R. ACS Cent. Sci. 2017, 3, 272–274.
DOI: 10.1021/acscentsci.7b00138

(49) “Nickel-Catalyzed Cross-Electrophile Coupling of Alkyl Fluorides: Stereospecific Synthesis of Vinylcyclopropanes” Erickson, L. W.; Lucas, E. L.; Tollefson, E. J.; Jarvo, E. R. J. Am. Chem. Soc. 2016, 138, 14006–14011.
DOI: 10.1021/jacs.6b07567

Highlighted in Synfacts 2017, 13, 63.
DOI:10.1055/s-0036-1589748

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(48) “Decarboxylative Alkyl–Alkyl Cross-Coupling Reactions” Konev, M. O.; Jarvo, E. R. Angew. Chem. Int. Ed. 201655, 11340–11342.
DOI: http://onlinelibrary.wiley.com/doi/10.1002/anie.201605593/abstract

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(47) “Intra- and Intermolecular Nickel-Catalyzed Reductive Cross-Electrophile Coupling Reactions of Benzylic Esters with Aryl Halides” Konev, M. O.; Hanna, L. E.; Jarvo, E. R. Angew. Chem. Int. Ed. 2016, 55, 6730–6733.
DOI: 10.1002/anie.201601206

Highlighted in Org. Process Res. Dev. 2016, 20, 1109−1117. DOI: http://pubs.acs.org/doi/pdf/10.1021/acs.oprd.6b00218

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(46) “Selective Cross-Electrophile Coupling Using Dual Catalysis” Hanna, L. E.; Jarvo, E. R. Angew. Chem. Int. Ed. 2015, 54, 15618. doi/10.1002/anie.201509444

Invited highlight.

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(45) “Silver-Catalyzed Enantioselective Propargylation Reactions of N-Sulfonylketimines.” Osborne, C. A.; Endean, T. B. D.; Jarvo, E. R. Org. Lett. 201517, 5340. DOI 10.1021/acs.orglett.5b02692

Highlighted in Synfacts 2016, 12, 14.
45-OL-Ag(44) “Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers with Isotopically-Labeled Grignard Reagents.”  Dawson, D. D.; Jarvo, E. R. Org. Proc. Res. Dev. 2015, 19, 1356. DOI: 10.1021/acs.oprd.5b00148

Invited contribution to special issue “Non-precious Metal Catalysis”

44-OPRD(43) “Stereospecific Intramolecular Reductive Cross-Electrophile Coupling Reactions for Cyclopropane Synthesis.  Tollefson, E. J.; Erickson, L. W. Jarvo, E. R. J. Am. Chem. Soc. 2015137, 9760. DOI:10.1021/jacs.5b03870

Highlighted in Org. Proc. Res. Dev. 201620, 105.
DOI: 10.1021/acs.oprd.6b00012
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(42) “Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers and Esters.” Tollefson, E. J.; Hanna, L. E.; Jarvo, E. R. Acc. Chem. Res. 2015, 48, 2344. Link

Invited contribution to special issue, “Earth Abundant Metals in Homogeneous Catalysis
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(41) “Selective synthesis of either enantiomer of an anti-breast cancer agent via a common enantioenriched intermediate.” Johnson, A. G.; Tranquilli, M. M.; Harris, M. R.; Jarvo, E. R. Tetrahedron Lett. 2015, 56, 3486. Link

Invited Manuscript for Symposium-In-Print in Memory of Professor Wasserman
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(40) “Stereospecific Cross-Coupling Reactions of Aryl-Substituted Tetrahydrofurans, Tetrahydropyrans, and Lactones.” Tollefson, E. J.; Dawson, D. D.; Osborne, C. A.; Jarvo, E. R. J. Am. Chem. Soc. 2014, 136, 14951. Link

Highlighted in Org. Proc. Res. Dev. 2015, 19, 322. DOI: 10.1021/acs.oprd.5b00022
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(39) “Enantiospecific Intramolecular Heck Reactions of Secondary Benzylic Ethers.” Harris, M. R.; Konev, M. O.; Jarvo, E. R. J. Am. Chem. Soc. 2014, 136, 7825. Link

Highlighted in Synfacts 2014, 10, 932.
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(38) “Diaryl and Heteroaryl Sulfides: Synthesis via Sulfenyl Chlorides and Evaluation as Selective Anti-Breast-Cancer Agents.” Yonova, I. M.; Osborne, C. A.; Morrissette, N. S.; Jarvo, E. R. J. Org. Chem. 2014, 79, 1947. Link
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(37) “Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents and Identification of Selective Anti-Breast-Cancer Agents.” Yonova, I. M.; Johnson, A. G.; Osborne, C. A.; Moore, C. E.; Morrissette, N. S.; Jarvo, E. R. Angew. Chem. Int. Ed. 2014, 53, 2422. Link

Highlighted as “Synfact of the Month” in Synfacts 2014, 10, 515.

(36) “Enantioselective Propargylation and Allenylation Reactions of Ketones and Imines.” Wisniewska, H. M.; Jarvo, E. R. J. Org. Chem. 2013, 78, 11629. Link
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(35) “Functional-Group-Tolerant, Nickel-Catalyzed Cross-Coupling Reaction for Enantioselective Construction of Tertiary Methyl-Bearing Stereocenters.” Wisniewska, H. M.; Swift, E. C.; Jarvo, E. R. J. Am. Chem. Soc. 2013, 135, 9083. Link
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(34) “Asymmetric Transition Metal-Catalyzed Cross-Coupling Reactions for the Construction of Tertiary Stereocenters.” Swift, E. C.; Jarvo, E. R. Tetrahedron 2013, 69, 5799. Link
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(33) “Silver-Catalyzed Allenylation and Enantioselective Propargylation Reactions of Ketones.”  Kohn, B. L.; Ichiishi, N.; Jarvo, E. R. Angew. Chem. Int. Ed. 2013, 52, 4414. Link

Highlighted in Synfacts 2013, 9, 766.
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(32) “Retention or Inversion in Stereospecific Nickel-Catalyzed Cross-Coupling of Benzylic Carbamates with Arylboronic Esters: Control of Absolute Stereochemistry with an Achiral Catalyst.”  Harris, M. R.; Hanna, L. E.; Greene, M. A.; Moore, C. E.; Jarvo, E. R. J. Am. Chem. Soc. 2013, 135, 3303. Link
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(31) “Synthesis of Enantioenriched Triarylmethanes by Stereospecific Cross-Coupling Reactions.” Taylor, B. L. H.; Harris, M. R.; Jarvo, E. R. Angew. Chem. Int. Ed. 2012, 51, 7790. Link
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 (30) “Traceless Directing Group for Stereospecific Nickel-Catalyzed Alkyl−Alkyl Cross-Coupling Reactions.” Greene, M. A., Yonova, I. M., Williams, F. J., Jarvo, E. R. Org. Lett. 2012, 14, 4293. Link

Highlighted in Synfacts 2012, 8, 1228.
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(29) “Developments in Transition-Metal Catalyzed Reactions Using Electrophilic Nitrogen Sources.” Barker, T. J., Jarvo, E. R. Synthesis, 2011, 24, 3954. Link
droppedImage-236(28) “Rhodium-Catalyzed Redox Allylation Reactions of Ketones.” F. J. Williams, R. E. Grote, E. R. Jarvo. Chem. Commun. 2012, 48, 1496. Link

Invited manuscript for “Emerging Investigators” Issue
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(27) “Regioselective Silver-Mediated Kondakov-Darzens Olefin Acylation.” Barczak, N. T., Jarvo, E. R. Chem.–Eur J. 2011, 17, 12912. Link
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(26) “Construction of Enantioenriched Tertiary Stereogenic Centers by Nickel- and Palladium-Catalyzed Cross-Coupling Reactions of Alkyl Electrophiles.” Taylor, B. L. H., Jarvo, E. R. Synlett, 2011, 19, 2761. Link

Invited highlight of Publication #19

(25) “Palladium-Catalyzed Annulation Reactions for Diastereoselective Cyclopentene Synthesis.” B. L. Kohn, E. R. Jarvo. Org. Lett. 2011, 13, 4858. Link
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(24) “Oxazolidine Synthesis by Complementary Stereospecific and Stereoconvergent Methods.” M. B. Shaghafi, R. E. Grote, E. R. Jarvo. Org. Lett. 2011, 13, 5188. Link
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(23) “Stereochemistry of Transmetalation of Alkylboranes in Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions.” B. L. H. Taylor, E. R. Jarvo. J. Org. Chem. 2011, 76, 7573. Link
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(22) “Titanium-Mediated Amination of Grignard Reagents using Primary and Secondary Amines.” T. J. Barker, E. R. Jarvo. Angew. Chem. Int. Ed. 2011, 50, 8325. Link

Highlighted in Synfacts 2011, 11, 1232.
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(21) “Palladium-Catalyzed Cascade Reaction for Synthesis of Substituted Isoindolines.” F. J. Williams, E. R. Jarvo. Angew. Chem. Int. Ed. 2011, 50, 4459. Link

Highlighted in Synfacts 2011, 7, 766.
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(20) “Enantioselective Silver-Catalyzed Propargylation of Aldimines.” H. M. Wisniewska, E. R. Jarvo. Chem. Sci. 20112, 807-810. Link

Highlighted in Synfacts 2011, 6, 646. Link
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(19) “Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Ethers: Enantioselective Synthesis of Diarylethanes.” B. L. H. Taylor, E. C. Swift, J. D. Waetzig, E. R. Jarvo. J. Am. Chem. Soc. 2011, 133, 389-391. Link

Highlighted in Synfacts 2011, 4, 351.
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(18) “Diene-Ligated Iridium Complexes as Catalysts for Allylation and Methallylation Reactions of Ketones.” T. J. Barker, E. R. Jarvo. Synthesis 2010, 19, 3259-3262. Link
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(17) “Umpolung Amination: Nickel-Catalyzed Coupling Reactions of N,N-Dialkyl-N-chloroamines with Diorganozinc Reagents” T. J. Barker, E. R. Jarvo J. Am. Chem. Soc. 2009131, 15598-15599. Link

Highlighted in Synfacts 2010, 2, 212.
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(16) “Diene-Ligated Iridium Catalyst for Allylation Reactions of Ketones and Imines” T. J. Barker, E. R. Jarvo Org. Lett. 2009, 11, 1047-1049. Link
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(15) “Palladium-Catalyzed, One-Pot, Three-Component Synthesis of Homoallylic Amines from Aldehyde Anisidine, and Allyl Trifluoroacetate” R. E. Grote, E. R. Jarvo Org. Lett. 2009, 11, 485-488.  Link
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(14) “Conjugate Allylation Reactions of Alkylidene Malononitriles Catalyzed by NHC-ligated Palladium Catalysts.”  J.D. Waetzig, E.C. Swift, E.R. Jarvo,Tetrahedron 2009, 65, 3197-3201. Link
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(13) “Silver-Catalyzed, Manganese-Mediated Allylation Reactions of Aldehydes and Ketones.”  N.T. Barczak, E.R. Jarvo, Eur. J. Org. Chem. 2008, 5507-5510.  Link
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(12) “Palladium-Catalyzed Conjugate Allylation of a,b-Unsaturated N-Acylpyrroles.”  M.B. Shaghafi, B.L. Kohn, E.R. Jarvo, Org. Lett. 2008, 10, 4743-4746Link

Highlighted in Nachrichten aus der Chemie 2009, 57, 6.
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(11) “Catalytic Umpolung Allylation of Aldehydes by π-Allylpalladium Complexes Containing Bidentate N-Heterocyclic Carbene Ligands.”  N.T. Barczak, R.E. Grote, E.R. Jarvo, Organometallics 2007, 26, 4863-4865.  Link
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(10) “Efficient Total Syntheses of (-)-Colombiasin A and (-)-Elisapterosin B:  Application of the Asymmetric Quinone Diels-Alder Reaction” A.A. Boezio, E.R. Jarvo, B.M. Lawrence, E.N. Jacobsen, Angew. Chem. Int. Ed2005, 44, 6046-6050.

(9) “Highly Enantio- and Regioselective Quinone Diels-Alder Reaction Catalyzed by a Tridentate [(Schiff Base CrIII)] Complex.” E.R. Jarvo, B.M. Lawrence, E.N. Jacobsen, Angew. Chem. Int. Ed. 2005, 44, 6043-6046.

(8) “Asymmetric Acylations.” E.R. Jarvo, S.J. Miller, Comprehensive Asymmetric Catalysis, Supplement 1; E.N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer-Verlag: Berlin, Heidelberg, 2004; Chapter 43.

(7) “Amino Acids and Peptides as Asymmetric Organocatalysts.” E.R. Jarvo, S.J. Miller, Tetrahedron 200258, 2481-2495.

(6) “Fluorescence-Based Screening of Asymmetric Acylation Catalysts Through Parallel-Enantiomer Analysis.  Identification of a Catalysts for Tertiary Alcohol Resolution.” E.R. Jarvo, C.A. Evans, G.T. Copeland, S.J. Miller J. Org. Chem. 2001, 66, 5522-5527.

(5) “Incorporation of Peptide Isosteres into Enantioselective Peptide-Based Catalysts as Mechanistic Probes.” M.M. Vasbinder, E.R. Jarvo, S.J. Miller. Angew. Chem. Int. Ed. 2001, 40, 2824-2827.

(4) “Asymmetric Acylation Reactions Catalyzed by Conformationally Biased Octapeptides.” E.R. Jarvo, M.M. Vasbinder, S.J. Miller. Tetrahedron 2000, 56, 9773-9779.

(3) “A Biomimetic Approach to Asymmetric Acyl Transfer Catalysis.” E.R. Jarvo, G.T. Copeland, N. Papaioannou, P.J. Bonitatebus, Jr., S.J. Miller. J. Am. Chem. Soc. 1999, 121, 11638-11643.

(2) “Minimal Acylase-Like Peptides. Conformational Control of Absolute Stereospecificity.” E.R. Jarvo, G.T. Copeland, S.J. Miller.  J. Org. Chem. 1998, 63, 6784-6785.

(1) “High-Pressure Diels-Alder Reactions of Quinone mono-ketals.” E.R. Jarvo, S.R. Boothroyde, M.A. Kerr. Synlett 1996, 879.